Pollution Prevention Technology Profile Trivalent Chromium Replacements for Hexavalent Chromium Plating
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I Fifteen Years of Outdoor Corrosion of Trivalent and Hexavalent Chromium Electrodeposits
hen the first trivalent chromium electroplating process was commercially introduced in the mid-l970s, information on the corrosion properties of the deposits and other physical properties was unknown. To obtain a comprehensive understanding about the corrosion properties of trivalent chromium electrodeposits over a variety of nickel deposits, chromium deposits from trivalent chromium electrolyt...
متن کاملTotal removal of heavy metal from mixed plating rinse wastewater ABSTRACT A mixed plating rinse wastewater containing zinc, hexavalent chromium, trivalent chromium, and cyanide with total dissolved solids
A mixed plating rinse wastewater containing zinc, hexavalent chromium, trivalent chromium, and cyanide with total dissolved solids of 424 mg/1 was treated by a model consisting of a sand filter and ion exchange columns. A strongly acidic cation resin in hydrogen form and a strongly basic anion resin in hydroxide form were used in the columns as cationic and anionic exchangers, respectively. The...
متن کاملPlating with Trivalent Chrome
Hexavalent chromium wastes need to be chemically reduced to trivalent chrome in the shop’s treatment plant. This necessitates the use of expensive chemicals such as sulfur dioxide, sodium metabisulfite or sodium borohydride. Also considerable hazardous sludge is generated during the neutralization step of the treatment process due to the high chromium concentration of the plating solutions. Haz...
متن کاملSoil humic acids may favour the persistence of hexavalent chromium in soil.
The interaction between hexavalent chromium Cr(VI), as K(2)CrO(4), and standard humic acids (HAs) in bulk solution was studied using three complementary analytical methods: UV-Visible spectroscopy, X-ray absorption spectroscopy and differential pulse stripping voltammetry. The observed UV-Vis and X-ray absorption spectra showed that, under our experimental conditions, HAs did not induce reducti...
متن کاملRemoval of hexavalent chromium of contaminated soil by coupling electrokinetic remediation and permeable reactive biobarriers.
PURPOSE In this study, a novel and ecological alternative have been developed to treat soils contaminated with hexavalent chromium coupling two well-known systems: electrokinetic remediation and permeable reactive biobarriers. The electric field promotes the electromigration of the hexavalent chromium oxyanions towards the anode. The biobarriers were placed before the anode electrode, in order ...
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تاریخ انتشار 2003